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Ikeura, Hiromi*; Sekiguchi, Tetsuhiro; Kitajima, Yoshinori*; Baba, Yuji
Applied Surface Science, 169-170, p.282 - 286, 2001/01
Times Cited Count:8 Percentile:44.9(Chemistry, Physical)Carbon and nitrogen K-shell excitation and dissociation of condensed formamide at 96 K were studied by near edge X-ray absorption fine structure (NEXAFS) recorded by total electron yield (TEY), total ion yield (TIY) and photon-stimulated desorption (PSD) yield of H+ measurements. It was found that electronic transitions from the C1s or the N1s to the *(C-H) and/or (N-H) enhanced ion yield of H+ from the C-H and/or N-H functional group. This selective dissociation indicates that the corresponding unoccupied molecular orbital has an antibonding character of the C-H and/or N-H. To investigate the molecular orientation of condensed formamide, incidence-angle-dependent TEY-NEXAFS spectra were measured. The CNO plane of the adsorbed formamide molecule is determined to be tilted away from the surface by an averaged angle of about 42 degrees.
Baba, Yuji; Sekiguchi, Tetsuhiro
Journal of Vacuum Science and Technology A, 18(2), p.334 - 337, 2000/03
Times Cited Count:4 Percentile:22.98(Materials Science, Coatings & Films)no abstracts in English
Baba, Yuji; Yoshii, Kenji; Sasaki, Teikichi
Surface Science, 376(1-3), p.330 - 338, 1997/00
Times Cited Count:25 Percentile:78.49(Chemistry, Physical)no abstracts in English
Baba, Yuji; G.Dujardin*; P.Feulner*; D.Menzel*
Hyomen Kagaku, 13(5), p.244 - 248, 1992/07
no abstracts in English
Baba, Yuji; G.Dujardin*; P.Feulner*; D.Menzel*
Physical Review Letters, 66(25), p.3269 - 3272, 1991/06
Times Cited Count:24 Percentile:78.27(Physics, Multidisciplinary)no abstracts in English
*; ; Ozawa, K.; *
JAERI-M 84-094, 174 Pages, 1984/05
no abstracts in English